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C2F2 lewis structure, geometric shape, polar or nonploar?

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Solution

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To determine the Lewis structure, geometric shape, and polarity of C2F2 (ethyne or acetylene), we will follow a systematic approach.

Step 1: Counting Valence Electrons
First, we need to count the total number of valence electrons available for the C2F2 molecule. Carbon (C) has 4 valence electrons, and fluorine (F) has 7 valence electrons.
First, we need to count the total number of valence electrons available for the C2F2 molecule. Carbon (C) has 4 valence electrons, and fluorine (F) has 7 valence electrons.

Total valence electrons = (Number of C atoms × 4) + (Number of F atoms × 7)
Total valence electrons = (2 × 4) + (2 × 7) = 8 + 14 = 22 valence electrons

Step 2: Drawing the Lewis Structure
Next, we draw the Lewis structure by following these steps:

1. Place the least electronegative atom in the center. In C2F2, carbon is less electronegative than fluorine, so the carbon atoms will be central.
2. Connect the outer atoms (fluorines) to the central atoms (carbons) with single bonds.
3. Distribute the remaining valence electrons as lone pairs on the outer atoms (fluorines) to complete their octet.
4. If the central atom does not have a complete octet, form double or triple bonds as necessary.

For C2F2, each carbon will form a triple bond with the other carbon to complete their octets, and each carbon will form a single bond with a fluorine atom. The Lewis structure will look like this:

$$
\text{F-C≡C-F}
$$

Each line represents a pair of shared electrons, and the triple line between the carbon atoms represents a triple bond.

Step 3: Determining the Geometric Shape
The geometric shape of a molecule is determined by the arrangement of atoms in space, which minimizes the repulsion between electron pairs according to the VSEPR (Valence Shell Electron Pair Repulsion) theory.

For C2F2, the central carbon atoms are bonded to one other carbon and one fluorine, with no lone pairs on the carbon atoms. This arrangement corresponds to a linear geometry because there are two regions of electron density around each carbon atom (the triple bond counts as one region, and the single bond to fluorine counts as another).

Step 4: Assessing Polarity
To determine if C2F2 is polar or nonpolar, we consider the electronegativity of the atoms and the symmetry of the molecule.

1. Electronegativity: Fluorine is more electronegative than carbon, so the C-F bonds are polar.
2. Molecular Symmetry: The molecule is symmetrical, with the polar C-F bonds oriented in opposite directions.

Because the polarities of the C-F bonds cancel each other out due to the linear and symmetrical shape of the molecule, C2F2 is considered a nonpolar molecule.

In summary, the Lewis structure of C2F2 consists of a triple bond between the two carbon atoms and single bonds between the carbon atoms and the fluorine atoms. The geometric shape of the molecule is linear, and due to its symmetrical structure, C2F2 is nonpolar.

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